H314 Causes severe skin burns and eye damage. Ingestion: Corrosive. 27 0 obj<>stream OSHA Status: The internal component (thionyl chloride) is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1920.1200. The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). Emits dense corrosive fumes in moist air. +T�Ϭzz���[��\�M�It��Gh��|����,Bj��,|8�=��o�j� ��J��TW�SU@2�"���։nl�ZU�YxF���Q*�J�%��Ԓ��d��!�H� ��k��Lת$M�2_��г�U_Z U�@=���,��T��ӥ4��{Xf���ܲ�� PM:�7�#�ҬUQ�z�����" Thionyl chloride is sold by various chemical suppliers, but due to its hazards it's generally not available to the amateur chemist. 12 - ECOLOGICAL INFORMATION When properly used or disposed, the Lithium-Thionyl chloride batteries do not present environmental hazard. 0000009613 00000 n Do not eat, drink or smoke when using this product. 0000007494 00000 n 0000004033 00000 n endstream endobj 25 0 obj<. 0000017598 00000 n Decisions that inherently pose a risk of injury or a hazard to human beings or property should not be made on the basis of this information. Thionyl chloride solution 2.0 M in methylene chloride; CAS Number: 7719-09-7; Linear Formula: Cl2OS; find Sigma-Aldrich-293121 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. 0000001311 00000 n <<1b2552d1b1366e49b0bd9b0d50bc0452>]>> * Thionyl Chloride can affect you when breathed in. Application Thionyl chloride may be used in the following processes: • To facilitate the synthesis of indenones from 3-hydroxyindanones via dehydroxylation. 169 F (76.1111 °C) NIOSH XM5150000 76 °C OU Chemical Safety Data (No longer updated) More details: 79 °C SynQuest M016-4-01: 79 °C Parchem – fine & specialty chemicals 89100: 168-170 F / 760 mmHg (75.5556-76.6667 °C / 760 mmHg) Wikidata Q409171 169 F / 760 mmHg (76.1111 °C / 760 mmHg) Wikidata Q409171 79 °C Sigma-Aldrich SIAL-18438: 75.7 °C / 760 mmHg Kaye & Laby (No longer … Please strictly observe safety instructions. Chronic –Overexposure can cause symptoms of non-fibrotic lung injury. 0000008223 00000 n 0000005178 00000 n Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Important additional information about respirator selection, Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride, Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. P270 Do not eat, drink or smoke when using this product. * Exposure to Thionyl Chloride can irritate the nose and throat. [Note: Fumes form when exposed to moist air. 0000002751 00000 n %%EOF 0000006724 00000 n National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Level TO THIONYL CHLORIDE-air: ceiling concentration 1 ppm: NIOSH* DHHS #92-100,1992: National Occupational Exposure Survey 1983 0000010294 00000 n 0000001391 00000 n 0000001570 00000 n The mixture of thionyl chloride with ethyl acetate in the presence of zinc or iron metal results in an explosively hazardous mixture. Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. 0000002717 00000 n Thionyl chloride is an inorganic compound with the chemical formula S O Cl 2.It is a moderately volatile colourless liquid with an unpleasant acrid odour. [The SOCl2 is converted to SO2 and sulfur chlorides. 0000003279 00000 n 0000003355 00000 n 5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. You will be subject to the destination website's privacy policy when you follow the link. Applicable part number: GAP-9419-H THAAD KVB . 0000020267 00000 n Its sale is regulated in many places. Lithium-Thionyl Chloride (Li-SOCl2) Battery 1/6 Document Number: RD-ER-201501-001 Issued date: 3 January 2015 EVE Energy Co., Ltd Safety and Reliability Lab MATERIAL SAFETY… H331 Toxic if inhaled. Wash face, hands and any exposed skin thoroughly after handling. The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. * Thionyl Chloride is a CORROSIVE CHEMICAL and contact can severely irritate and burn the skin and eyes with possible eye damage. Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 minutes. Safety considerations of lithium-thionyl chloride cells The use of spirally wound lithium-thionyl chloride (Li-SOCl2) cells is currently limited because of their hazardous behavior. SECTION 2- HAZARD(S) IDENTIFICATION Classification: The batteries described in this SDS are hermetically sealed articles. Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. Toxic exposure to fumes of Thionyl Chloride reacting with water may result in a delayed pulmonary response (longer than two weeks) of bronchiolitis Obliterans-inflammation of the bronchioles. * Breathing Thionyl Chloride can irritate the lungs causing Signs and symtoms of exposure :Eye and mucous membrane irritation. Hazard statement (s) H302 Harmful if swallowed. the larynx and bronchi, chemical pneumonitis, and pulmonary edema. CDC twenty four seven. Since most reactions using SOCl 2 evolve these gases, they should be performed only in well‐ventilated hoods. Violently reacts with water to liberate hydrochloric acid and sulfur dioxide [NFPA 10th ed. 0000002248 00000 n Precautionary statement(s ) P261 Avoid breathing vapours. Purification Methods: Crude SOCl2 can be freed from sulfuryl chloride, sulfur monochloride and sulfur dichloride by refluxing it with sulfur and then fractionally distilling twice. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. Lithium Thionyl Chloride Battery. Because all cells and batteries are defined as “articles”,they are exempt from the requirements of the Hazard Communications Standard. Precautionary Statements. Saving Lives, Protecting People, The National Institute for Occupational Safety and Health (NIOSH), National Institute for Occupational Safety and Health, A – NIOSH Potential Occupational Carcinogens, B – Thirteen OSHA-Regulated Carcinogens, D – Substances with No Established RELs, E – OSHA Respirator Requirements for Selected Chemicals, G – 1989 Air Contaminants Update Project: Exposure Limits NOT in Effect, Type C & CE – Definitions for Type C and Type CE Respirators, U.S. Department of Health & Human Services. Chronic: Chronic exposure may cause effects similar to those of acute exposure. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. 0000005516 00000 n Shipping Requirements: Lithium metal batteries and cells are subject to the shipping requirements and exceptions under 49 CFR 173.185. 5.2 Special hazards arising from the substance or mixture Sulphur oxides, Hydrogen chloride gas Container explosion may occur under fire conditions. 0000001174 00000 n %PDF-1.5 %���� Toxic exposure to fumes of Thionyl chloride reacting with water may result in delayed pulmonary response, bronchiolitis Oblitereans(inflammmation of the bronchioles). H332 Harmful if inhaled. Not applicable unless there is exposure to an electrolyte. CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. For this reason, improper handling of the battery could lead to distortion, leakage, overheating, explosion, fire, or generation of irritating/corrosive gases and cause human injury or equipment trouble. Inhalation of sulfuryl chloride or thionyl chloride vapors can result in pulmonary edema. The Saft primary Lithium-Thionyl chloride batteries do not contain toxic materials. 0000004730 00000 n 1991]. startxref Certain batteries contain small amounts of thionyl chloride, but it's impractical to extract it. trailer 0000005773 00000 n It is toxic, reacts with water, and is also listed under the Chemical Weapons Convention as it may be used for the production of chemical weapons. ], Water, acids, alkalis, ammonia, chloryl perchlorate 0000002795 00000 n This is a high energy density sealed battery containing (Lithium) and (Thionyl Chloride) materials. Thionyl chloride should be stored in glass containers at ambient temperature and protected from moisture. 0000008902 00000 n 500g. 0000021119 00000 n Harmful if swallowed. Shop a large selection of products and learn more about Thionyl chloride, 99%, Alfa Aesar. 0000000016 00000 n Thionyl Chloride: 1.635 Not applicable unless there is exposure to an electrolyte. Binary mixtures of these components seem stable, while ternary mixtures result in spontaneously violent reactions. OSHA HazCom compliant labels are made with chemical & solvent resistant materials. 0000001761 00000 n Causes gastrointestinal/digestive tract burns. GHS SDS requirements and classification criteria do … Thionyl chloride. 0000006028 00000 n ], inhalation, ingestion, skin and/or eye contact, irritation eyes, skin, mucous membrane; eye, skin burns, Centers for Disease Control and Prevention. thionyl chloride Thionyl dichloride thionyl dichoride; Thionyl dichloride; Show more chemical information. HAZARD SUMMARY * Thionyl Chloride can affect you when breathed in. Thionyl chloride is an inorganic compound with the chemical formula SOCl 2. * Thionyl Chloride is a CORROSIVE CHEMICAL and contact can severely irritate and burn the skin and eyes with possible eye damage. H314 Causes severe skin burns and eye damage. Thionyl chloride is an inorganic acid chloride mainly used as a reagent to prepare carboxylic acid chlorides from carboxylic acids. Thionyl chloride is an inorganic compound with the chemical formula SOCl2. It is a moderately volatile colourless liquid with an unpleasant acrid odour. Thionyl Chloride CAS No 7719-09-7 MATERIAL SAFETY DATA SHEET SDS/MSDS. Use only outdoors or in a well-ventilated area. It reacts with water to liberate the toxic gases HCl and SO 2 . Safety hazards have ranged from mild venting of toxic materials to violent explosions and fires. Thionyl chlorideRevision Date 14-Feb-2020. Hazard statement(s ) H302 Harmful if swallowed. * Exposure to Thionyl Chloride can irritate the nose and throat. xref Thionyl chloride is listed on schedule 3 of the Chemical Weapons Convention and ordering large amounts may draw attention of the authorities. Thionyl chloride is widely used to convert carboxylic acids and alcohols to the corresponding acyl chlorides and alkyl chlorides respectively via an internal nucleophilic substitution. 0000000892 00000 n Precautionary statement (s) Prevention. 24 29 Suitable products for Thionyl chloride SOCl 2. It is a moderately volatile colourless liquid with an unpleasant acrid odour. Sulfinyl chloride, Sulfur chloride oxide, Sulfurous dichloride, Sulfurous oxychloride, Thionyl dichloride Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide. May cause respiratory irritation. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Sulfur Dioxide gas will be created in 0.25 … 0 The internal component (thionyl chloride) is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1920.1200. 24 0 obj<> endobj UN1836 Thionyl chloride, Hazard class: 8; Labels: 8-Corrosive material. P264 Wash ... thoroughly after handling. * Breathing Thionyl Chloride can irritate the lungs causing coughing and/or shortness of breath. Partition coefficient: n None known -octanol/water Not applicable unless there is exposure to an electrolyte. 13 - DISPOSAL CONSIDERATIONS Dispose in accordance with applicable regulations which vary from country to country. [Note: Fumes form when exposed to moist air.] 0000003034 00000 n Thionyl chloride reacts vigorously with water to generate gaseous HCl and SO2. Prevention. [Note: Reacts violently with water to form sulfur dioxide & hydrogen chloride. Thionyl chloride is primarily used as a chlorinating reagent, with approximately 45,000 tonnes (50,000 short tons) per year being produced during the early 1990s. Buy Thionyl Chloride GHS Labels from HCL & clearly identify hazards. Solubility in other solvents Thionyl Chloride: Decomposes violently on contact with water. Air. on other Federal or private website oxides, Hydrogen chloride gas Container explosion may occur under fire.... Sulfur chlorides hazards have ranged from mild venting of toxic materials acid chlorides from carboxylic acids is converted to and! Irritate the lungs causing coughing and/or shortness of breath to violent explosions fires! Explosion may occur under fire conditions internal component ( Thionyl chloride is a CORROSIVE chemical and can... The larynx and bronchi, chemical pneumonitis, and pulmonary edema larynx and bronchi, chemical pneumonitis, pulmonary... 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2020 thionyl chloride hazards